摘要
氢氟烯烃具有良好的环境相容性(ODP=0,GWP值低)和优异的工作性能,在制冷、发泡、清洗、刻蚀和灭火等领域越来越受到人们的关注和重视。同时,该类化合物也是生产含氟精细化学品和高分子材料的基础原料。综述了新型C4含氟烯烃(包括六氟异丁烯、八氟-2-丁烯、七氟丁烯和六氟-2-丁炔)的制备方法和应用领域。
For good environmental compatibility(ODP = 0,low GWP) and excellent working performance,hydrogen-fluorine olefins(HFOs) have been paid more and more attention in the area of refrigeration,foaming,cleaning,etching and extinguishing.In addition,HFOs are also basic material of fluorine-containing fine chemicals and polymers.The synthetic methods and applications of novel C4 fluorine-containing olefins including hexafluoro-isobutene,octafluoro-2-butene,heptafluorobutene,hexafluoro-2-butyne were reviewed in this paper.
作者
吴海锋
黄瑛
丁元胜
刘武灿
Wu Haifeng;Huang Ying;Ding Yuansheng;Liu Wucan(Zhejiang Research Institute of Chemical Industry Co., Ltd., State Key Laboratory Fluorinated Greenhouse Gases Replacement and Control Treatment, Hangzhou 310023, of China)
出处
《有机氟工业》
CAS
2017年第3期38-43,50,共7页
Organo-Fluorine Industry
关键词
氢氟烯烃
六氟异丁烯
八氟-2-丁烯
七氟丁烯
六氟-2-丁炔
hydrogen-fluorine olefins(HF0s )
hexafluoroisobutene
octafluoro-2-butene
heptafluoro-butene
hexafluoro-2-butyne