全氟甲基乙烯醚合成研究进展

Progress in the Synthesis of Perfluoromethyl Vinyl Ether

对近年来相关合成文献和专利进行了总结,通过以全氟甲基乙烯基醚(PMVE)的合成方法为例,可以为全氟烷基乙烯基醚系列衍生物C_nF_(2n+1)OCF=CF_2的合成技术提供借鉴。现有合成方法可分为催化法、热解法、还原法和含氟砌块法。

The synthetic methods of perfluoromethyl vinyl ether in literatures and patents were summarized in this paper.Tack synthetic methods of perfluoromethyl vinyl ether for example,provided perfluoroalkyl vinyl ether derivative series CnF（2n＋1）OCF = CF2 synthetic route technology.Existing synthetic methods were divided into catalytic method,pyrolysis method,reduction method and fluorine block method.