期刊文献+

Porous Organic Frameworks-derived Porous Carbons with Outstanding Gas Adsorption Performance

Porous Organic Frameworks-derived Porous Carbons with Outstanding Gas Adsorption Performance
原文传递
导出
摘要 A series of porous carbon materials was synthesized via high temperature pyrolysis from well-defined and thermally stable precursors, namely porous organic frameworks(POFs), in inert atmosphere. The porous carbon materials showed enhanced gas adsorption capacities together with increased heat of adsorption and stronger affinity between the frameworks and the gases as compared to the precursor materials. To exemplify, sample C-POF-TBBP-1000 with a high BET surface area of 1290 m^2/g can adsorb 2.8 mmol/g CH4(273 K, 101.325 kPa), 5.4 mmol/g CO2(273 K, 101.325 kPa) and 2.2% H2(mass fraction, 77 K, 101.325 kPa), thereby surpassing most other porous adsorbent materials reported till date. The study highlights the potential of porous carbons derived from novel porous organic framework structures for gas adsorption applications. A series of porous carbon materials was synthesized via high temperature pyrolysis from well-defined and thermally stable precursors, namely porous organic frameworks(POFs), in inert atmosphere. The porous carbon materials showed enhanced gas adsorption capacities together with increased heat of adsorption and stronger affinity between the frameworks and the gases as compared to the precursor materials. To exemplify, sample C-POF-TBBP-1000 with a high BET surface area of 1290 m^2/g can adsorb 2.8 mmol/g CH4(273 K, 101.325 kPa), 5.4 mmol/g CO2(273 K, 101.325 kPa) and 2.2% H2(mass fraction, 77 K, 101.325 kPa), thereby surpassing most other porous adsorbent materials reported till date. The study highlights the potential of porous carbons derived from novel porous organic framework structures for gas adsorption applications.
机构地区 College of Chemistry
出处 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2018年第3期338-343,共6页 高等学校化学研究(英文版)
基金 Supported by the National Natural Science Foundation of China(Nos.21390394, 21471065) and the "111" Project of China (No.B07016).
关键词 Porous organic framework Gas adsorption PYROLYSIS Porous carbon Porous organic framework Gas adsorption Pyrolysis Porous carbon
  • 相关文献

参考文献1

共引文献2

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部