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Solubility of red palm oil in supercritical carbon dioxide: Measurement and modelling 被引量:1

Solubility of red palm oil in supercritical carbon dioxide:Measurement and modelling
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摘要 The solubility of red palm oil(RPO) in supercritical carbon dioxide(scCO_2) was determined using a dynamic method at 8.5–25 MPa and, 313.15–333.15 K and at a fixed scCO_2 flow rate of 2.9 g·min^(-1) using a full factorial design. The solubility was determined under low pressures and temperatures as a preliminary study for RPO particle formation using scCO_2. The solubility of RPO was 0.5–11.3 mg·(g CO_2)^(-1) and was significantly affected by the pressure and temperature. RPO solubility increased with pressure and decreased with temperature. The Adachi–Lu model showed the best-fit for RPO solubility data with an average relative deviation of 14% with a high coefficient of determination, R^2 of 0.9667, whereas the Peng–Robinson equation of state thermodynamic model recorded deviations of 17%–30%. The solubility of red palm oil (RPO) in supercritical carbon dioxide (scCO2) was determined using a dynamic method at 8.5-25 MPa and, 313.15-333.15 K and at a fixed scCO2 flow rate of 2.9 g. mn -1 using a full factorial design. The solubility was determined under low pressures and temperatures as a preliminary study for RPO par- ticle formation using scCO2. The solubility of RPO was 0.5-11.3 mg. (g CO2) -1 and was significantly affected by the pressure and temperature. RPO solubility increased with pressure and decreased with temperature. The Adachi-Lu model showed the best-fit for RPO solubility data with an average relative deviation of 14% with a high coefficient of determination, R2 of 0.9667, whereas the Peng-Robinson equation of state thermodynamic model recorded deviations of 17%-30%.
出处 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2018年第5期964-969,共6页 中国化学工程学报(英文版)
基金 supported by Geran Putra IPS(Vote No.:9469400),University Putra Malaysia
关键词 溶解度数据 二氧化碳 scCO2 建模 测量 相对偏差 低压力 动态方法 Solubility Supercritical carbon dioxide Mathematical modelling Thermodynamics Palm oil
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