摘要
Perovskite-based solar cell technology has advanced significantly and the power conversion efficiencies are nowadays on par with commercialized photovoltaic technologies. To realize the potential of perovskite solar cells, the focus is now shifting to scalable fabrication technologies that will enable low-cost solution processing of perovskite solar cells over large areas and with high yields. This review article discusses the fundamental concerns that arise when transitioning from laboratory to large area solution coating, available scalable coating technologies, and their applicability to the fabrication of high-performance perovskite solar cells. We find that a significant amount of work has been done to test scalable coating technologies, but also that often the methods that led to highest-performing cells in the laboratory （e.g. antisolvent processing） show limited compatibility with scalable coating methods. To achieve a high-yield and low-cost process, development must emphasize a high degree of control provided by sequential conversion of perovskite films and engineering of additives that fine-tune coating properties of perovskite precursor inks.
Perovskite-based solar cell technology has advanced significantly and the power conversion efficiencies are nowadays on par with commercialized photovoltaic technologies. To realize the potential of perovskite solar cells, the focus is now shifting to scalable fabrication technologies that will enable low-cost solution processing of perovskite solar cells over large areas and with high yields. This review article discusses the fundamental concerns that arise when transitioning from laboratory to large area solution coating, available scalable coating technologies, and their applicability to the fabrication of high-performance perovskite solar cells. We find that a significant amount of work has been done to test scalable coating technologies, but also that often the methods that led to highest-performing cells in the laboratory （e.g. antisolvent processing） show limited compatibility with scalable coating methods. To achieve a high-yield and low-cost process, development must emphasize a high degree of control provided by sequential conversion of perovskite films and engineering of additives that fine-tune coating properties of perovskite precursor inks.
基金
supported by funding from the Energy Materials and Surface Sciences Unit of the Okinawa Institute of Science and Technology Graduate University
the OIST R&D Cluster Research Program
the OIST Proof of Concept(POC)Program
JSPS KAKENHI Grant Number 15K17925
