多孔有机聚合物非均相光催化研究进展

Progress of Porous Organic Polymers in Heterogeneous Photocatalysis

多孔有机聚合物(POPs)是一类新型功能高分子材料,具有高比表面积、良好的稳定性及易于功能化等优点,已在气体存储与分离、传感、有机光电和多相催化等领域表现出潜在的应用。本文综述了在可见光激发下,多孔有机聚合物作为非均相光催化剂催化有机转化的研究进展,分析了多孔有机聚合物光催化剂的结构设计理念,总结了光催化有机反应的类型及催化性能,最后对多孔有机聚合物在光催化有机合成中的应用前景进行了展望,希望能够给予从事相关工作的科研工作者一定的思路和启发。

Porous organic polymers （POPs） are a kind of new functional polymer materials, which have the advantages of high specific surface area, good stability and easy functionalization. POPs have shown potential applications in gas storage and separation, sensing, organic photoelectries and heterogeneous catalysis. This review summarizes the progress for organic conversions by POPs as heterogeneous photocatalysts under visible light excitation. The structural design concept of POPs based photocatalysts was analyzed. And the types and catalytic properties of photocatalytic organic reactions by POPs were summarized. Finally, the existing problems and the opportunities of POPs in this field were also evaluated. We hope that this paper can give some ideas and inspirations to researchers engaged in relevant work.