多孔高分子材料对二氧化碳的捕获与转化

The Capture and Conversion of Porous Polymer Materials for CO_2

在温和的条件下,运用化学技术进行有效的碳捕获和碳转换是减少人为CO_2排放的重要途径。近年来,多孔有机聚合物(Porous organic polymers,POPs)由于其优异的CO_2吸附性能,被视为最具潜力的CO_2捕获材料而引起了广泛的关注。本文介绍了4种POPs的最新研究进展,包括金属有机骨架材料(Metalorganic frameworks,MOFs)、沸石咪唑酯骨架材料(Zeolitic Imidazolate Frameworks,ZIFs)、共轭微孔聚合物(Conjugated microporous polymers,CMPs)、共价有机骨架材料(Covalent organic frameworks,COFs),并对MOFs和CMPs作为催化剂和吸附剂在室温条件下CO_2的捕获与转化过程的相关实验研究工作进行了综述。

It is the main strategy to conceive efficient carbon capture or conversion to reduce the anthropogenic CO2 emission via chemical technologies under moderate temperature conditions. Recently, porous organic polymers （POPs） have attracted intense attention because of their ultra-high CO2 adsorption capacity and potential applications as novel adsorbents. In this paper, we introduce the recent research progress of four kinds of POPs, including Metal-organic frameworks（MOFs）, Zeolitic Imidazolate Frameworks （ZIFs）, Conjugated microporous polymers （CMPs）, Covalent organic frameworks（COFs）. And CO2 capture and transformation using MOFs or CMPs as catalyst and sorbent under ambient conditions are reviewed.