摘要
A series of random copolypeptides of poly（methoxy-diethylene glycol–L-glutamate）-co-poly（S-（onitrobenzyl）-L-cysteine）was synthesized by ring-open copolymerization of methoxydiethylene glycol-Lglutamate-N-carboxyanhydride（EG2-Glu-NCA） and S-（o-nitrobenzyl）-L-cysteine-N-carboxyanhydride（NBC-NCA） in dried dimethylformamide solution, which presents quadruple thermo-photo-redox responsive self-assembly behavior and forms the related nanogel and hydrogel in water.
A series of random copolypeptides of poly（methoxy-diethylene glycol–L-glutamate）-co-poly（S-（onitrobenzyl）-L-cysteine）was synthesized by ring-open copolymerization of methoxydiethylene glycol-Lglutamate-N-carboxyanhydride（EG2-Glu-NCA） and S-（o-nitrobenzyl）-L-cysteine-N-carboxyanhydride（NBC-NCA） in dried dimethylformamide solution, which presents quadruple thermo-photo-redox responsive self-assembly behavior and forms the related nanogel and hydrogel in water.
基金
the financial support of the National Natural Science Foundation of China (No. 21474061)
