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Basic formation mechanisms of Lake Doroninskoye soda water, East Siberia, Russia

Basic formation mechanisms of Lake Doroninskoye soda water,East Siberia,Russia
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摘要 The primary scientific goal of studying salt lakes is to better understand the formation of small continentaltype hydrogeochemical systems. Many scientists have attributed the metamorphism of the chemical composition of salt lakes to the evaporative concentration of water. However, the formation of soda water is inconsistent with this hypothesis. Thus, analyzing intrabasinal biochemical processes and water—rocks interactions during the evaporative concentration of water allows us to understand the major mechanisms of the formation and evolution of water compositions. Therefore, the aim of this paper is to identify the key processes involved in the formation of the chemical composition of the water in Lake Doroninskoye. An analysis of the distribution of major components shows that Na^+,HCO^-_3, CO^(2-)_3, and Cl-are dominant in this water. High concentrations of these elements are the result of evaporative water concentration. Calcium, magnesium, and potassium are not accumulated because the water is saturated in minerals containing these elements. The main barrier to the growth of the sulfate content of water is sulfate reduction.This process also contributes to the additional reproduction of carbon dioxide, which reacts with the products of the hydrolysis of aluminosilicates OH-to form HCO^-_3 and CO^(2-)_3, thus further contributing to the natural processes of soda formation. The primary scientific goal of studying salt lakes is to better understand the formation of small continental- type hydrogeochemical systems. Many scientists have attributed the metamorphism of the chemical composition of salt lakes to the evaporative concentration of water. How- ever, the formation of soda water is inconsistent with this hypothesis. Thus, analyzing intrabasinal biochemical pro- cesses and water--rocks interactions during the evaporative concentration of water allows us to understand the major mechanisms of the formation and evolution of water com- positions. Therefore, the aim of this paper is to identify the key processes involved in the formation of the chemical composition of the water in Lake Doroninskoye. An analysis of the distribution of major components shows that Na+, HCO3-, CO32-, and C1- are dominant in this water. High concentrations of these elements are the result of evaporative water concentration. Calcium, magnesium, and potassium are not accumulated because the water is saturated in min- erals containing these elements. The main barrier to the growth of the sulfate content of water is sulfate reduction. This process also contributes to the additional reproduction of carbon dioxide, which reacts with the products of the hydrolysis of aluminosilicates OH- to form HCO3- and CO32-, thus further contributing to the natural processes of soda formation.
出处 《Acta Geochimica》 EI CAS CSCD 2018年第4期546-558,共13页 地球化学学报(英文)
基金 financially supported by the Russian Science Foundation The interaction mechanisms, equilibrium state and evolution trend of the salt waters and brines-basic and ultrabasic rocks systems (on the example of Siberian platform areas) (RSF Project No. 17-17-01158)
关键词 苏打水 流水 西伯利亚 机制 东方 俄国 生物化学 硫酸盐 Saline lake Sulfate reduction Thermodynamic equilibrium
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