期刊文献+

3-乙基-2-乙酰吡嗪缩4-甲基氨基硫脲Ni(Ⅱ)/Zn(Ⅱ)配合物的合成、结构和DNA结合性质(英文) 被引量:1

Ni(Ⅱ)/Zn(Ⅱ) Complexes with 1-(3-Ethylpyrazin-2-yl)ethylidene)-4-methylthiosemicarbazide: Crystal Structures and DNA-Binding Properties
下载PDF
导出
摘要 合成并通过单晶衍射、元素分析、红外光谱表征了配合物[Ni L(HL)](OAc)(1)和[Zn L(OAc)]n(2)的结构(HL=3-乙基-2-乙酰吡嗪缩4-甲基氨基硫脲)。单晶衍射结果表明,配合物1中的Ni髤离子与来自2个缩氨基硫脲配体的4个N原子和2个S原子配位,其中一个配体为阴离子。而配合物2中,五配位的Zn髤离子采取扭曲的四方锥配位构型,与2个μ-OCO桥联的醋酸根,一个三齿配位的缩氨基硫脲阴离子配位,形成沿a轴方向的一维链状结构。此外,荧光光谱结果表明,配合物与DNA的相互作用强于配体。 Two complexes [Ni L(HL)](OAc)(1) and [Zn L(OAc)]n(2)(HL =1-(3-ethylpyrazin-2-yl)ethylidene)-4-methylthiosemicarbazide) have been synthesized and structurally determined by single-crystal X-ray diffraction.The results show that the Ni (Ⅱ) ion in 1 is surrounded by two independent thiosemicarbazone ligands with N4 S2 donor set, one of which is anionic. However, in complex 2, the Zn (Ⅱ) ion with a distorted tetragonal pyramid coordination geometry is five-coordinated, involving two μ-OCO acetate anions, one tridentate enolizated ligand L-, thus forming one dimension chain-like framework along a axis. Moreover, the fluorescence spectra indicate that the interactions of the complexes with DNA are stronger than that of the thiosemicarbazone ligand. CCDC:1587278, 1; 1587280, 2.
作者 王碗碗 王元 于亚平 宋雨飞 吴伟娜 WANG Wan-Wan;WANG Yuan;YU Ya-Ping;SONG Yu-Fei;WU Wei-Na(College o f Chemistry and Chemical Engineering,Henan Key Laboratory o f Coal Green Conversion,Henan Polytechnic University,Jiaozuo,Henan 454000,Chin)
出处 《无机化学学报》 SCIE CAS CSCD 北大核心 2018年第8期1511-1516,共6页 Chinese Journal of Inorganic Chemistry
基金 国家自然科学基金(No.21001040) 河南省自然科学基金(No.182300410183,162300410011)资助项目
关键词 吡嗪 缩氨基硫脲 配合物 晶体结构 DNA结合性质 pyrazine thiosemicarbazone complex crystal structure DNA-binding property
  • 相关文献

同被引文献2

引证文献1

二级引证文献2

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部