摘要
以商品级腈纶纤维(1)为原料,1,6-己二胺(Ⅰ)为胺化试剂,制得含伯胺基的腈纶纤维(2);由糊状叶绿素经酯交换反应合成脱镁叶绿酸a甲酯(Ⅱ);将Ⅱ接枝到胺化纤维2上制备了含叶绿素衍生物的功能化腈纶纤维(3),其结构经IR、元素分析和SEM表征。并对制备条件进行了优化。
A primary-amine functionalized fiber（2） was prepared by introducing 1,6-diaminohexane（Ⅰ） onto commercial polyacrylonitrile fiber（1）. Methyl pheophorbide-a（Ⅱ） was prepared by transesterification of paste chlorophyll. The chlorophyll derivative functionalized fiber（3） was prepared by introducing Ⅱ onto 2. The structure was characterized by IR,elemental analysis and SEM. The preparation conditions were optimized.
作者
郑力硕
陶敏莉
ZHENGLi-shuo;TA(Department of Chemistry,School of Science,Tianjin University,Tianjin 300350,China;Collaborative Innovation Center of Chemical Science and Engineering（Tianjin）,Tianjin 300072,China)
出处
《合成化学》
CAS
CSCD
北大核心
2018年第7期503-507,共5页
Chinese Journal of Synthetic Chemistry
基金
国家自然科学基金资助项目(21572156)
关键词
腈纶纤维
己二胺
脱镁叶绿酸a甲酯
功能化纤维
制备
polyacrylonitri le f iber
1,6-diaminohexane
methyl pheophorbide- a
functionalized fiber
preparation
