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纳米CaCO_3对水泥-石灰石粉浆体流变作用 被引量:4

Rheological properties of cement-ground limestone paste with nano-CaCO_3
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摘要 试验采用Rheolab QC型旋转黏度计测试了掺纳米CaCO_3的水泥-石灰石粉浆体的流变曲线,应用Herschel-Bulkley流变模型对其剪切应力-速度(τ-γ)曲线进行拟合,得到浆体的动态屈服应力、稠度系数和流变指数,并用触变环面积表征浆体的触变性。结果表明:随石灰石粉掺量的增加,水泥-石灰石粉浆体的动态屈服应力逐渐减小,稠度系数增大,触变性先增大后减小;纳米CaCO_3未改变水泥-石灰石粉浆体的流变类型都呈现出剪切稀化行为;随纳米CaCO_3掺量的增加,水泥-石灰石粉浆体动态屈服应力和稠度逐渐增大,触变性减小,纳米CaCO_3使水泥-石灰石粉浆体流变性能变差,但使其稳定性增强。 The rheological curves of the cement-ground limestone paste were determined by Rheolab QC rotation viscometer.Dynamic yield stress,consistency coefficient and rheological index of the paste were obtained by fitting the measuredτ-γcurves based on Herschel-Bulkley model and thixotropy was characterized by the area of thixotropic hysteresis loop.The results indicate that:with the increase of ground limestone content,dynamic yield stress decreases gradually,consistency coefficient increases,while thixotropy increases and then decreases.The addition of nano-CaCO3 has little effect on the rheological type of the cement-ground limestone paste and they both present a shear thinning behavior.With the increase of nano-CaCO3 content,dynamic yield stress and consistency coefficient increase gradually,while thixotropy decreases.The addition of nano-CaCO3 results in a poor rheological properties of the cement-ground limestone pastes but enhances its stability.
作者 肖佳 周书会 王大富 彭扬轩 范波 XIAO Jia;ZHOU Shuhui;WANG Dafu;PENG Yangxuan;FAN Bo(School of Civil Engineering,Central South University,Changsha 410075,China;Communication and Signal Construction Corporation Limited,Changsha 410005,China;School of Civil Engineering,Shangqiu Institute of Technology,Shangqiu 476000,China)
出处 《复合材料学报》 EI CAS CSCD 北大核心 2018年第8期2185-2190,共6页 Acta Materiae Compositae Sinica
基金 国家自然科学基金(51278497)
关键词 纳米CACO3 石灰石粉 动态屈服应力 稠度系数 触变性 nano-CaCO3 ground limestone dynamic yield stress consistency coefficient thixotropy
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