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AgIO3 Composited with m-BiVO4 as Enhanced Visible-light Heterojunction Photocatalysts for the Elimination of Aqueous Organic Pollutants

AgIO_3 Composited with m-BiVO_4 as Enhanced Visible-light Heterojunction Photocatalysts for the Elimination of Aqueous Organic Pollutants
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摘要 The heterojunction strategy was used to overcome the drawbacks of AgIO3 for its wide band gap and of BiVO4 for its low charge-separation efficiency. The photocatalytic per-formances of the as-prepared AgIO3/BiVO4 were assessed by the photodegradation of rhodamine B(Rh B) and tetracycline hydrochloride antibiotics(TC) under visible-light irradiation. All the as-prepared samples showed remarkable enhanced photocatalytic efficiency than pure AgIO3 and BiVO4. Especially, 40% AgIO3/BiVO4 exhibited optimum photocatalytic activities among all the prepared samples. The improvements may be ascribed to the synergetic effect between AgIO3 and BiVO4 including matching potentials and effective charge separation. Radical trap experiments determined that h+ radical plays a significant role in the photodegradation of RhB while e-is not the dominating reactive species. The heterojunction strategy was used to overcome the drawbacks of AgIO3 for its wide band gap and of BiVO4 for its low charge-separation efficiency. The photocatalytic per-formances of the as-prepared AgIO3/BiVO4 were assessed by the photodegradation of rhodamine B(Rh B) and tetracycline hydrochloride antibiotics(TC) under visible-light irradiation. All the as-prepared samples showed remarkable enhanced photocatalytic efficiency than pure AgIO3 and BiVO4. Especially, 40% AgIO3/BiVO4 exhibited optimum photocatalytic activities among all the prepared samples. The improvements may be ascribed to the synergetic effect between AgIO3 and BiVO4 including matching potentials and effective charge separation. Radical trap experiments determined that h+ radical plays a significant role in the photodegradation of RhB while e-is not the dominating reactive species.
出处 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2018年第7期1160-1168,共9页 结构化学(英文)
基金 supported by the National Natural Science Foundation of China(41672278) the Projects of Fujian Provincial Department of Education(JAT160340) the Fujian Provincial Natural Science Foundation Projects(2017Y4001) the Science and Technology Plan Projects of Fuzhou(2017-G-96,2017-G-90) the Scientific Research Projects Funded Start-up Funds of Fujian University of Technology(GY-Z160065) National Undergraduate Training Program for Innovation and Entrepreneurship(201710388074)
关键词 AgIO3 BIVO4 heterojunction photocatalysis AgIO3 BiVO4 heterojunction photocatalysis
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