摘要
通过分层涂浆制备表层涂碳的MlNi(3.93)Co(0.46)Mn(0.27)Al(0.34)/Co3O4CeO2电极,并建立表层涂碳的MlNi(3.93)Co(0.46)Mn(0.27)Al(0.34)/Co3O4CeO2电极反应机理模型。物理表征结果表明,活性碳(AC)具有高比表面积,为二维结构,贮氢合金呈块状固体,为单相的CaCu5型六方结构;电化学测试结果表明,活性碳形成双电层的同时也作为导电剂在MlNi(3.93)Co(0.46)Mn(0.27)Al(0.34)/Co3O4CeO2电极表面形成导电网络,可改善贮氢合金电极的电化学性能,在0.2C充放电下,放电比容量292.6mAh·g-1,以1500mAh·g-1倍率放电时,高倍率放电性能(HRD值)为82.5%,循环100次后容量保持率95.91%,在50%DOD下,氢扩散系数及交换电流密度依次为4.7×10-11cm2·s-1,315.6mA·g-1,相比于未涂炭的MlNi(3.93)Co(0.46)Mn(0.27)Al(0.34)/Co3O4CeO2电极,分别提高了2.4mAh·g-1、20.94%、5.53%、38.2%、34.5%。
Carbon coated MlNi(3.93)Co(0.46)Mn(0.27)Al(0.34)/Co3O4CeO2 electrode was prepared by layered coating method and the reaction mechanism model of MlNi(3.93)Co(0.46)Mn(0.27)Al(0.34)/Co3O4CeO2-electrode was established. Physical characterization results show that the active carbon( AC) has a two-dimensional structure with high specific surface area,and the MlNi(3.93)Co(0.46)Mn(0.27)Al(0.34)/Co3O4CeO2-alloy is block solid with structure of single-phase Ca Cu5 six-party. Electrochemical testing results indicate that the conductive agent AC can form a double electrical layer structure and acts as conductive agent to form a conductive network on the surface of MlNi(3.93)Co(0.46)Mn(0.27)Al(0.34)/Co3O4CeO2 electrode,which effectively improves the electrochemical performance of hydrogen storage alloys. Compared to the MlNi(3.93)Co(0.46)Mn(0.27)Al(0.34)/Co3O4CeO2-electrode with no carbon coating,the discharge specific capacity of carbon coated MlNi(3.93)Co(0.46)Mn(0.27)Al(0.34)/Co3O4CeO2-electrode was 292. 6 m Ah·g-1 and retention capacity was 95. 91% after 100 cycles at 0. 2 C,and HRD value was 82. 5% under the current density of 1500 m Ah·g-1,the hydrogen diffusion coefficient was 4. 7×10-11 cm2·s-1 and the exchange current density was 315. 6 m A·g-1 under 50% DOD,which were increased by 2. 4 m Ah·g-1,20. 94%,5. 53%,38. 2% and 34. 5%,respectively.
作者
蒋志军
马志鸿
赵文怡
张旭霞
王哲
JIANG Zhi-jun;MA Zhi-hong;ZHAO Wen-yi;ZHANG Xu-xia(Zibo Guoli New Power Source Technology Co.,Ltd.,Zibo 255086,China;Baotou Haoming Rare Earth New Power Source Technology Co.,Ltd.,Baotou 014030,China;Zibo Junking Power Source Technology Co.,Ltd.,Zibo 255086,China;Baotou Research Institute of Rare Earths,Baowu 014030,China;National Engineering Research Center of Rare Earth Metallurgy and Functional Materials,Baotou 014030,China)
出处
《稀土》
EI
CAS
CSCD
北大核心
2018年第4期143-151,共9页
Chinese Rare Earths
基金
山东省自主创新专项项目(2013CXH10401)
山东省重点研发计划(2017GSF16102)
淄博市科技发展计划项目(2015kj100149)
淄博市校城融合发展计划(2017ZBXC070)
关键词
NI-MH电池
贮氢合金
活性碳
双电层
电化学性能
Ni-MI-I battery
hydrogen storage alloy
active carbon
electric double layer
electrochemical performance