摘要
采用通用法制备了石墨烯负载超细硫化锌(ZnS-G)和石墨烯负载超细硫化镉(CdS-G)的复合物。通过扫描电子显微镜(SEM)、透射电子显微镜(TEM)、X射线衍射仪(XRD)、傅里叶变换红外光谱仪(FT-IR)等手段对样品进行了形貌观察和物相分析,并讨论了氧化石墨烯对复合物形貌的影响。研究结果表明,ZnS-G和CdS-G具有优异的光催化效果,氧化石墨烯用量为2%(wt,质量分数)条件下制得的ZnS-G,在紫外光照射50min,对甲基橙的降解率达到89.1%;氧化石墨烯用量为4%(wt,质量分数)条件下制得的CdS-G,在可见光照射100min,对甲基橙的降解率达到75.6%。
A general approach was developed to prepare graphene decorated ultra fine ZnS(CdS)(ZnS(CdS)-G).Morphology was characterized via scanning electron microscopy(SEM),transmission electron microscopy(TEM),X-ray diffraction pattern(XRD)and fourier transform infrared spectrometer(FT-IR).The effect of graphene oxide(GO)on the morphology of ZnS(CdS)-G was discussed.The water treatment results showed that ZnS-G and CdS-G had the excellent photocatalytic performance.When the GO mass fraction was 2 wt% and 89.1% of MO can be degraded under UV-light by ZnS-G in 50 min.When the GO mass fraction was 4 wt%,75.6% of MO can be degraded under visible-light by CdS-G in 100 min.
作者
曾斌
曾武军
陈丹
刘万锋
金灿
Zeng Bin;Zeng Wujun;Chen DanI;Liu Wanfeng;Jin Can(College of Mechanical Engineering,Hunan University of Arts and Science,Changde 415000;Hunan Collaborative Innovation Center for Construction and Development of Dongting Lake Ecological Economic Zone,Changde 415000)
出处
《化工新型材料》
CAS
CSCD
北大核心
2018年第8期25-28,33,共5页
New Chemical Materials
基金
国家自然科学基金资助项目(51272073)
湖南省自然科学基金(2017JJ2191)
湖南省高校产学研合作示范基地"凿岩机械研发与产业化"(XJT[2014]239)
湖南文理学院重点项目(17ZD01)
关键词
石墨烯
超细
水处理
graphene
ultra fine
water treatment