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纤维素螯合树脂的合成及其对金离子的提取 被引量:2

Synthesis of Cellulose-based Chelating Resins for Absorption of Gold Ions
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摘要 利用废报纸中的纤维素与含双烯酮的苯 -正己烷混合溶液在 70℃下反应 1.5 h,制备含乙酸乙酰基团的螯合树脂。结果表明 ,在 p H=7.2 2的水溶液中 ,纤维素螯合树脂可以有效地吸附金离子达 90 %以上 。 The cellulose from waste newspaper was used in the preparation of a chelating resin containing acetoacetate groups by reacting cellulose with diketene in a mixed solution of benzene and nI-hexane at 70℃ for 1.5 hours. The results indicated that in aqueous solution of pH=7.22, the cellulose-based chelating resins have an absorption efficiency of gold ions more than 90% and they could be used repeatedly.
机构地区 东北大学化学系
出处 《辽宁工学院学报》 2002年第4期49-51,共3页 Journal of Liaoning Institute of Technology(Natural Science Edition)
关键词 纤维素 合成 金离子吸附 螯合树脂 水溶液 乙酰乙酸化 cellulose acetoacetate gold ion absorption chelating resin
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  • 1刘峙嵘,韦鹏,曾凯,周利民.R-520树脂吸附金的研究[J].黄金,2006,27(8):33-35. 被引量:6
  • 2刘春萍,关若飞,王妮.磁性功能化酚醛树脂的合成及对金属离子的吸附性能[J].应用化学,2006,23(9):1037-1041. 被引量:3
  • 3Al-Merey R Hariri Z Abu Hilal J. Selective separation of gold from iron ore samples using ion exchange resin [ J ]. Microchemical Journal. 2003, 75 (3): 169-177.
  • 4Donia A M, Elwaked K Z. Gold(Ⅲ) recovery using synthetic chelating resins with anione, thio and amine/mercaptan functionalities[J]. Separation and purification Technology, 2005,42 : 111 - 116.
  • 5Aria. A A Adsorption of silver(Ⅰ) and gold(Ⅲ) on resins derived from bisthiourea and application to retrieval of silver ions from processed photo films . Hydrometallutgy[J]. 2005,80 ( 1/2 ) : 98 - 106.
  • 6Prasetyo J. Park E Y. Waste paper sludge as a potential biomass for bio-ethanol production [J]. Korean Journal ofChemical Engineering. 2013,30(2):253-261.
  • 7KhongkrapanP. Tippayawong N,Kiatsiriroat T. Thermochemical conversion of waste papers to fuel gas in amicrowave plasma reactor[J]. Journal of Clean Energy Technologies. 2013,1(2):80-83.
  • 8KalpanaD. Cho S H,Lee S B,et al. Recycled waste paper - a new source of raw material for electric double-layer capacitors[J]. Journal of Power Sources. 2009,190(2) :587-591.
  • 9KopinskiL. Kwiatkowska-Marks S. Utilization of waste newspaper using oyster mushroom mycelium [J]. Industrial &Engineering Chemistry Research. 2012, 51(11):4440-4444.
  • 10MatsushitaK. Shimada M, Okayama T. Adsorption Properties of Bisphenol A on Activated Carbon Prepared fromWastepaper[J]. Sen,i Gakkaishi, 2009, 65( 11) :287-291.

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