摘要
以4-溴苯腈为起始原料经过Miyanra硼化反应、Suzuki偶联反应和溴化反应等合成了4’-(4-溴萘-1-基)[1,1’-联苯基]-4-腈.通过~1H NMR、^(13)C NMR表征了化合物的结构,通过TG、荧光发射光谱等研究了标题化合物的发光效率和稳定性.
4’-(4-Bromonaphthalene-1-yl)[1,1’-biphenyl]-4-nitrile was synthesized by Miyanra reaction,Suzuki reaction and bromination reaction by using 4-bromobenzonitrile as a raw material in this paper. The structureof synthesized compound was characterized by 1H NMR and 13C NMR. Thermal properties and optical properties ofthe title compound were determined with TG and fluorescence spectrum.
作者
吴威
化林
陈俊强
赵燕
王荣
刘铁良
WU Wei1, HUA Lin2, CHEN Junqiang3, ZHAO Yan2, WANG Rong2, LIU Tieliang2(1. Henan Petroleum and Chemical Infornmtion, Zhengzhou 450003, China; 2. Institute of Chemistry Co. Ltd., Henan Academy of Sciences, Zhengzhou 450002, China; 3. Institute of Energy Co. Ltd., Henan Academy of Sciences, Zhengzhou 450008, China)
出处
《河南科学》
2018年第9期1352-1356,共5页
Henan Science
基金
河南省科技创新人才计划项目(174100510018)
河南省科技开放合作项目(17210600063)