期刊文献+

石墨相氮化碳及其改性对有机污染物的光催化降解 被引量:4

Photocatalytic Degradation of Organic Pollutants by Graphite Phase Carbon Nitride and its Modification
下载PDF
导出
摘要 光催化技术可以通过半导体材料光催化剂对太阳能进行有效吸收,且在较为温和的条件下可以发生光催化氧化还原反应,促进环境有机污染的降解。石墨相氮化碳(g-C_3N_4)是一种新型非金属半导体光催化剂,因自身独特的类石墨层状结构而具有良好的光催化性能,使其成为近年来光催化领域的研究热点之一。文章分析了g-C_3N_4的结构、性质和光催化机理,阐述了进一步提高其光催化活性的改性方法,并介绍了其在有机污染物光催化降解与环境修复领域的应用前景。 Photocatalytic technology can be used for effective absorption of solar energy through a semiconductor photocatalyst.Under the condition of moderate temperature,photocatalytic oxidation reduction reaction can occur to promote the degradation of organic pollution of the environment.Graphite-phase carbon nitride (g-C 3N 4) is a new type of non-metallic semiconductor photocatalyst with excellent photocatalytic properties due to its unique graphite-like lamellar structure,which makes it one of the hot spots in the field of photocatalysis in the recent years.In this paper,the structure and properties of g-C 3N 4 and light catalytic mechanism are analyzed.Furthermore,the modified method of further improving the photocatalytic activity is illustrated,and its application in the fields of photocatalytic degradation of organic pollutants and environmental remediation is introduced.
作者 李佳宇 李法云 王艳杰 邢杨 吝美霞 Li Jiayu;Li Fayun;Wang Yanjie;Xing Yang;Lin Meixia(Institute of Eco-environmental Sciences,Liaoning Shihua University,Fushun 113001,China;National & Local United Engineering Laboratory of Petroleum Chemical Process Operation,Optimization and Energy Conservation Technology,Fushun 113001,China;College of Resources and Environment,Hunan Agricultural University,Changsha 410128,China)
出处 《环境保护科学》 CAS 2018年第5期56-62,共7页 Environmental Protection Science
基金 国家自然科学基金(41571464) 辽宁省教育厅优秀人才项目(LR2015035)资助
关键词 石墨相氮化碳(g—C3N4) 改性 光催化 有机污染物 Graphite Phase Carbon Nitride ( g - C3N4 ) Modification Photocatalysis Organic Contaminant
  • 相关文献

参考文献11

二级参考文献89

  • 1Li Huiquan,Cui Yumin,Hong Wenshan,Hua Lin,Tao Dongliang.Photodegradation of methyl orange by BiOI-sensitized TiO_2[J].Rare Metals,2012,31(6):604-610. 被引量:10
  • 2林智虹,董锦昱,郑曦,陈日耀,陈震.电生成高铁酸盐及其对酚类废水处理机制的研究[J].福建师范大学学报(自然科学版),2004,20(3):54-58. 被引量:4
  • 3胡安正.纳米科技与纳米材料的应用研究[J].郧阳师范高等专科学校学报,2005,25(6):39-43. 被引量:3
  • 4柳松,谢添华,张正国,颜燕琼.掺钒TiO_2粉末的制备及光催化活性[J].华南理工大学学报(自然科学版),2007,35(6):91-96. 被引量:4
  • 5Fujishima A, Honda K. Electrochemical photolysis of wa- ter at a semiconductor electrode [ J ]. Nature, 1972,238: 37 -39.
  • 6Chen X B, Liu L, Yu P Y, et al. Increasing solar absorp- tion for photoeatalysis with black hydrogenated titanium dioxide nanocrystals [ J ]. Science,2011,331:746-750.
  • 7Wang X C, Maeda K, Thomas A, et al. A metal free poly- meric photocatalyst for hydrogen production from water under visible light[ J]. Nat Mater,2009(8) :76-80.
  • 8Chen X F, Zhang J S. Fe-g-C3 N4-Catalyzed oxidation of benzene to phenol using hydrogen peroxide and visible light [ J ]. J Am C hem Soc, 2009,131 : 11658 - 11659.
  • 9Groenewolt M, Antonietti M. Synthesis of g-C3 N4 nanopar- ticles in mesoporous silica host matrices [ J ]. Adv Mater, 2005,17 : 1789-1792.
  • 10Yan S C, Li Z S, Zou Z G. Photodegradation performance of g-C3N4 fabricated by directly heating melamine [ J ]. Langrauir,2009,25 ( 17 ) : 10397-10401.

共引文献219

同被引文献39

引证文献4

二级引证文献20

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部