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Karstedt催化剂及其抑制剂的研究进展 被引量:5

Studies on Karstedt catalyst and its inhibitor
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摘要 综述几种硅氢加成反应Karstedt催化剂及抑制剂的研究进展,并概述其在LED封装材料合成方面的应用。硅氢加成作为一种重要的合成反应在工业生产上应用广泛,是多种有机硅化合物合成的关键步骤。传统Karstedt催化剂催化活性高,但活化时间短,给工业生产和实际应用带来诸多不便,寻找常温可控催化剂具有很大应用价值。 Research progresses of several hydrosilylation Karstedt catalysts for hydrosilylation inhibitors were reviewed.Applications of these catalysts in synthesis of LED packaging material w and their ere brief- ly overviewed. As an important synthesis reaction, hydrosilylation is widely used in industrial production and is key step in synthesis of various organic silicon compounds. Traditional Karstedt catalyst has high catalytic activity, but life time is too short which brings a lot of inconvenience to industrial production and practical application. It is of great application value to find controllable catalyst at room temperature.
作者 谢云飞 饶秋华 李瑜 朱皓 Xie Yunfei;Rao Qiuhua;Li Yu;Zhu Hao(Department of Basic,Naval University of Engineering,Wuhan 430033,Hubei,China)
出处 《工业催化》 CAS 2018年第9期11-15,共5页 Industrial Catalysis
关键词 催化剂工程 硅氢加成 Karstedt催化剂 催化剂抑制剂 catalyst engineering hydrosilylation Karstedt catalyst catalyst inhibitor
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  • 1闫继娜,李亮,华子乐,陈航榕,阮美玲,李蕾,施剑林.MCM-41负载氧化铜活性组分的结构及其氢程序升温还原特性[J].硅酸盐学报,2005,33(4):452-455. 被引量:8
  • 2Karstedt B D. Platinum complexes of unsaturated siloxanes and platinum containing organopolysiloxanes: US,3775452[P]. 1973-11-27.
  • 3Yamamoto K, Hayashi T,Kumada M. Asymmetric homogeneous hydrosilylation with platinum(II) complexes of ehiral phosphines[J]. J Am Chem Soc,1971,93(20) :5301-5302.
  • 4Fink W. Tetrakis(triphenylphosphine)platinum(0), a catalyst for selective hydrosilylation[J]. Helv Chim Acta,1971,54(5) : 1304-1310.
  • 5朱士荣.浅析硅氢加成反应添加剂[J].化工之友,2006,11:4041.
  • 6van Leeuwen P W N M, Rivillo D, Raynal M, et al. Enantioselective supramolecular catalysis induced by remote clalraL cllOlSkJA. 3 ykIIl Chem Soc,2011,133(46) :18562 18565.
  • 7Zhang F S, Wang L D, Chang S H, et al. Phosphorescent ir(iii) complexes with both cyclometalatechromophores and phosphine-silano late ancillary: concurrent conversion of organosilane to silanolat[J]. Dalton Trans,2013,42(19) :7111 7119.
  • 8Zhou G J, Wang Q, Wang X Z, et al. Metallophosphors o{ platinum with distinct main-group elements: a versatile approach towards color tuning and white light emission with superior efficiency/color quality/brightness trade-offs[J]. J Mater Chem, 2010,20(35) :7472 7484.
  • 9Shin J, Bertoia J, Czerwinski K R,et al. A new homogeneous polymer support based on syndiotactie polystyrene and its application in palladium catalyzed Suzuki Miyaura cross coupling reactions[J]. Green Cbem,2009,11 (10) : 1576-1580.
  • 10Li Y H, Lu 1. Q, Das S, etal. General and selective copper catalyzed reduction of tertiary and secondary phosphine oxides: convenient synthesis of phosphines[J]. J Am Chem Soc,2012,134(23):9727 9732.

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