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Highly reversible lead-carbon battery anode with lead grafting on thecarbon surface 被引量:6

Highly reversible lead-carbon battery anode with lead grafting on the carbon surface
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摘要 A novel C/Pb composite has been successfully prepared by electmless plating to reduce the hydrogenevolution and achieve the high reversibility of the anode of lead-carbon battery (LCB). The depositedlead on the surface of C/Pb composite was found to be uniform and adherent to carbon surface. Becauselead has been stuck on the surface of C/Pb composite, the embedded structure suppresses the hydrogenevolution of lead-carbon anode and strengthens the connection between carbon additive and sponge lead.Compared with the blank anode, the lead-carbon anode with C/Pb composite displays excellent charge-discharge reversibility, which is attributed to the good connection between carbon additives and leadthat has been stuck on the surface of C/Pb composite during the preparation process. The addition of CIPb composite maintains a solid anode structure with high specific surface area and power volume, andthereby, it plays a significant role in the highly reversible lead-carbon anode. A novel C/Pb composite has been successfully prepared by electmless plating to reduce the hydrogenevolution and achieve the high reversibility of the anode of lead-carbon battery (LCB). The depositedlead on the surface of C/Pb composite was found to be uniform and adherent to carbon surface. Becauselead has been stuck on the surface of C/Pb composite, the embedded structure suppresses the hydrogenevolution of lead-carbon anode and strengthens the connection between carbon additive and sponge lead.Compared with the blank anode, the lead-carbon anode with C/Pb composite displays excellent charge-discharge reversibility, which is attributed to the good connection between carbon additives and leadthat has been stuck on the surface of C/Pb composite during the preparation process. The addition of CIPb composite maintains a solid anode structure with high specific surface area and power volume, andthereby, it plays a significant role in the highly reversible lead-carbon anode.
出处 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2018年第6期1674-1683,共10页 能源化学(英文版)
基金 the financial support provided by the National Natural Science Foundation of China (No.21573093) the National Key Research and Development Program (No.2017YFB0307501) Guangdong Innovative and Entrepreneurial Research Team Program (No.2013C092)
关键词 Lead-carbon battery Carbon/lead composite Charge acceptance Hydrogen evolution Electrochemically active surface area Lead-carbon battery Carbon/lead composite Charge acceptance Hydrogen evolution Electrochemically active surface area
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