摘要
The direct coupling of allylic alcohols with arylboronic acids or their derivatives catalyzed by Ni（cod）2 in the presence of a catalytic amount of base has been developed. A wide variety of allylic substrates or aryIboronic acids turned out to be applicable to this catalytic system. The present method does not require the use of ligands for stabilizing the nickel catalyst in most cases or additional activators for activation of altylic alcohols.
The direct coupling of allylic alcohols with arylboronic acids or their derivatives catalyzed by Ni（cod）2 in the presence of a catalytic amount of base has been developed. A wide variety of allylic substrates or aryIboronic acids turned out to be applicable to this catalytic system. The present method does not require the use of ligands for stabilizing the nickel catalyst in most cases or additional activators for activation of altylic alcohols.
基金
We thank the National Key Research and Development Pro- gram （No. 2016YFA0202900}, the National Natural Science Foundation of China （No. 21772217）, Science and Technology Commis- sion of Shanghai Municipality （No. 18XD1405000）, the Strategic Priority Research Program of the Chinese Academy of Sciences （No. XDB20000000）, and Shanghai Institute of Organic Chemistry （sioczz201807） for financial support.
