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三维荧光与高分辨率质谱技术在溶解性有机物结构解析中的研究进展 被引量:5

THREE-DIMENSIONAL FLUORESCENCE SPECTROSCOPY AND HIGH FIELD FT-ICR MASS SPECTROMETRY IN THE ANALYSIS OF DISSOLVED ORGANIC STRUCTURES
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摘要 三维荧光光谱耦合平行因子分析技术(EEM-PARAFAC)可解析溶解性有机物结构,但目前对PARAFAC拟合组分的性质尚不了解,高分辨率质谱能从分子层级解析溶解性有机物结构;本文总结近年来三维荧光光谱技术(EEM-PARAFAC)及高分辨率质谱技术(FT-ICR-MS)用于溶解性有机物研究进展,介绍了两种技术的表征方法和应用情况,分析了两种技术的发展、联系以及目前面临的问题与挑战。 Three-dimensional fluorescence spectrometry coupled with the parallel factor analysis(EEM-PARAFAC) can be used to analyze the structure of dissolved organic compounds. However, the molecular signatures associated with PARAFAC components are poorly defined. High-resolution mass spectrometry can resolve the dissolved organic structure from the molecular level. In this paper, recent advances in three-dimensional fluorescence spectroscopy(EEM-PARAFAC) and high-resolution mass spectrometry(FT-ICR-MS) were summarized. The principles, characterization methods, and applications of the two technologies were introduced. The relationship and challenges between the two technologies were analyzed.
作者 罗崇佳 陈浩 廖振良 LUO Chong-Jia;CHEN Hao;LIAO Zhen-liang(Tongji University,Shanghai 200092,China;Shanghai Academy of Environmental Sciences,Shanghai 200233,China)
出处 《能源环境保护》 2018年第5期1-6,共6页 Energy Environmental Protection
基金 国家自然科学基金项目(51578396) 国家自然科学基金项目(51778451) 国家重点研发计划项目(2016YFE0123300)资助
关键词 溶解性有机污染物 三维荧光光谱 FT-ICR-MS Dissolved organic matter Three-dimensional fluorescence spectroscopy FT-ICR-MS.
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