TNAZ的硝基甲烷法合成研究

Synthesis of TNAZ via Nitromethane

采用硝基甲烷法 ,经五步反应合成了 TNAZ,总收率在 4 0 %以上 ,并对其中关键反应的机理进行了初步探讨。

The title compound, a known melt castable high performance explosive, was synthesized starting with commercially available nitromethane and formaldehyde via a 5 step process. The overall yield was above 40%. Also, the mechanisms of ring closing/dehydration and oxidative nitration were elucidated in light of literatures.