新型超分子化合物(H_3NCH_2CH_2NH_3)_2[(HPO_4)_2Mo_5O_(15)]的晶体结构

Hydrothermal synthesis and crystal structure of a novel super molecular compound (H_3NCH_2CH_2NH_3)_2[(HPO_4)_2Mo_5O_(15)]

首次通过水热方法合成了新型超分子化合物 (H3NCH2 CH2 NH3) 2[(HPO4 ) 2 Mo5 O15 ]的晶体结构 ,并通过X衍射进行了结构表征 ,晶体学数据为 :单斜晶系 ,C2 /c空间群 ,a =1 7666( 4 )nm ,b =1 .0 0 3 4 ( 2 )nm ,c =1 .3 767( 3 )nm ,α =90°,β =96 90 ( 3 )°,γ =90°,ν =2 42 2 7( 8)nm3,Z =4,R =0 0 43 1 ,wR2 =0 1 2 87.

A novel super molecular compound,(H 3NCH 2CH 2NH 3) 2[(HPO 4) 2Mo 5O 15 ],was hydrothermally synthesized and structurally characterized by single crystal X-ray diffraction.The compound crystallizes in monoclinic space,group C2/c with a= 1 766 6(4) nm, b =1 003 4(2)nm, c =1 376 7(3)nm, α=90°,β=96 90(3)°,γ=90°,V=2 422 7(8) nm 3, Z=4,R=0 0431,wR 2=0 128 7.