摘要
Objectics A convenient method was developed for the determination of the enantioselectivity ofreversible kinetic resolutions with the new equation deduced by us. Methods By using the data of extent ofconversions at t1, 2t1, and the equilibrium constant K measured by usual method, the enantiomeric ratio E can beeasily calculated by the newly developed equation. Results We have successfully applied our method to theanalyses of enantioselectivity of three lipasic resolutions. The results are in good agreement with those of otherexperiments. Conclusion The method is simple and practical, and plays an important role in the determination ofkinetic data of reversible resolution.
Objectics A convenient method was developed for the determination of the enantioselectivity ofreversible kinetic resolutions with the new equation deduced by us. Methods By using the data of extent ofconversions at t1, 2t1, and the equilibrium constant K measured by usual method, the enantiomeric ratio E can beeasily calculated by the newly developed equation. Results We have successfully applied our method to theanalyses of enantioselectivity of three lipasic resolutions. The results are in good agreement with those of otherexperiments. Conclusion The method is simple and practical, and plays an important role in the determination ofkinetic data of reversible resolution.
