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EXAFS Study on Structure of Sulfided K—Co—Mo Catalysts

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摘要 Mixed alcohol is of great promise as octane improver in automotive fuel,and hopeful to replace the MTBE to reduce the environmental pollution,In this field,alkali-promted molybdenum-based catalysts have been given special interest because of their excellent sulfur-tolerance for synthesis of mixed alcohol from CO+H2,It was reported that the coblat is a favorable promoter for enhancing alcohol production,especially for improving the selectivity for C2+ alcohol[1-3],moreover,strong interaction between Con and Mo is in favor of mixed alcohol synthesis[4].Recently,we prpared a kind of K-Co-Mo ultrafine particles by sol-gel method and it shows much smaller particle size but higher activty and selectivity toward alcohol formation than the one prepared by conventional method[5],The aim of the present work is to research the micostructures of the Mo and Co species in the K-Co-Mo samples prepared by different method.
作者 BaoJun LiuTao
出处 《Beijing Synchrotron Radiation Facility》 2001年第1期37-40,共4页 北京同步辐射装置(英文版)
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