原子转移自由基聚合及其在新型高分子材料合成中的应用

ATOM TRANSFER RADICAL POLYMERIZATION AND SYNTHESIS OF NOVEL POLYMERIC MATERIALS

概述了原子转移自由基聚合 (ATRP)反应的基本原理、引发体系的组成及应用此技术来设计制备一系列指定拓朴结构和功能化的新型聚合物材料。ATRP是一种用途广泛、简单易行、有很好的工业应用前景的聚合技术。

This review systemtically introduces the initiating systems, mechanism of ATRP, and some novel model polymers synthesized by this method. ATRP is a versatile, sample and robust system which allows for the preparation of a wide variety of polymeric materials. ATRP allows an rather wide range of monomers to be polymerized and has defined the conditions required to modify the processes to allow preparation of gradient, block, graft, comb shapes and dendritic, star, organic and inorganic hybrids materials in organic or aquous system. It is believed that these processes are presenting at a state that should allow evaluated from an industrial or commercialization standpoint, of their potential impact in the marketplace.