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Inflnence of PH on Chemical Forms of Phosphate Ad-sorbed on Goethite Snrfaces

Inflnence of PH on Chemical Forms of Phosphate Ad-sorbed on Goethite Snrfaces
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摘要 Chemical forms of the phosphate adsorbed on goethite surfaces and characteristics of the coordinategroups which exchange with P on goethite surfaces in solutions with different pll values were investigated.Results showed that the chemical forms of P on goethite surfaces changed from the dominance of monodentatecorrdination to that of bidentate one with increasing pH of the solution. By influencing types of phosphateions in solutions, pH affected the chemical forms of P on goethite surfaces. The amount of OH ̄- displacedby phosphate on goethite surfaces was the most at pH 7.0, the second at pH 9.0, and the least at pH 4.5. InflnenceofPHonChemicalFormsofPhosphateAd-sorbedonGoethiteSnrfacesLIUFAN ̄1;JIEXIAO-LEIl ̄1;ZHOUDAI-HUA ̄1;LlXUE-YUAN ̄1;HEJI-ZHE...
出处 《Pedosphere》 SCIE CAS CSCD 1995年第2期157-162,共6页 土壤圈(英文版)
关键词 GOETHITE PH phosphate adsorption X-ray photoelectron spectroscopy 土壤P pH值 针铁矿表面 磷酸盐吸附 化学形态
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