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pH Effect on kinetics of Heavy Metal Sorption in Soils 被引量:1

pH Effect on Kinetics of Heavy Metal Sorption in Soils
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摘要 The pH effect on the sorption kinetics of heavy metals in soils was studied using a Constant flow leaching method. The soil samples were red soil collected from Yingtan, Jiangxi, and yellow-browp soil from Nabing,Jiangsu. The heavy metals tested were zinc and cadmium.Assuming that the experimental data fitted to the following kinetic rate equation: 1/c dx/dt=kx∞-kx,the rate constant k of sorption could be determined from the slope of the straight line by plotting of 1/c.dx/dt vs. x. The results showed that the pH effect on the rate constants of heavy mental sorption in soils was very significant. The values of k decreased with inpeasing pH. The sorptions were more sensitive to pH in red soil than in yellow-brown soil. The pH effect on the sorption kinetics of heavy metals in soils was studied using a constant flow leaching method.The soil samples were red soil collected from Yingtan,Jiangxi,and yellow-brown soil from Nanjing,Jiansu,The heavy metals tested were zinc and cadmium.Assuming that the experimental data diffed to the following kinetic rate equation:1/c.dx/dt=kx∞-kx,the rate constant k of sorption could be determined from the slope of the straight line by plotting of 1/c,dx/dt vs.x.The results showed that the pH effect on the rate constants of heavy mental sorption in soils was very significant.The values of k decreased with increasing pH.The sorptions were more sensitive to pH in red soil than in yellow-brown soil.
出处 《Pedosphere》 SCIE CAS CSCD 1994年第3期225-231,共7页 土壤圈(英文版)
关键词 heavy metals KINETICS SOILS SORPTION 土壤吸附 重金属吸附 动力学 pH值 土壤污染
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