摘要
以邻苯二胺为起始原料,与邻香兰素反应得到配体(H2L),用H2L与醋酸锌反应得到Zn L,再分别与水合氯化稀土、水合硝酸稀土(La=Gd、Nd、Pr、Sm)反应得到8个Salen型异双核金属金属配合物。通过红外光谱、紫外光谱等对合成产物进行了表征。
The ligand H2 L was obtained by o- phenylenediamine as the starting material and o- vanillin.Further,the H2 L was reacted with zine acetate and Zn L was obtained. Finally,eight salen- type heterobinuclear metal complexes were gotten by the reaction of Zn L and hydrated chloride rare- earth and nitric acid rare earth(( La = Gd,Nd,Pr,Sm). The products were characterized with IR and UV spectrum.
出处
《辽东学院学报（自然科学版）》
CAS
2015年第4期234-237,266,共5页
Journal of Eastern Liaoning University:Natural Science Edition
基金
国家级大学生创新实验项目(201411779035)
关键词
异双核金属配合物
邻苯二胺
邻香兰素
氯化稀土
硝酸稀土
heterobinuclear metal complex
o-phenylenediamine
o-vanillin
rare earth chloride
nitric acid rare earth
