摘要
Water-soluble rare earth elements (WSREEs) of four typical soil profiles in China were determined by using a high-resolution inductively coupled plasma mass spectrometer. Results showed that the contents of WSREEs decreased from upper layer to lower layer of soils in the southern part of China with a high rainfall and low pH but increased for soils in the northern part of China with a low rainfall and relatively higher pH. Contents of WSREEs in soils were lower than 100 μg kg-1 in most casest and varied greatly with both different soils and different layers of the same profile. The highest content was 2816.3 μg kg-1 but the lowest was 17.6 μg kg-1 only. The content of individual rare earth iement (REE) in the soil solution also varied greatly with the highest one ranging from 8.4 to 1373 μg kg-1 for Ce and the lowest one from 0.05to 4.48 μg kg-1 for Lu. The sum of WSREEs in the first soil layers ranged from 121.5 to 345.6 μg kg-1.Great variations existed among ratios of REEs extracted with water to the total REEs of soils, ranging from 0.02×10-3 to 13.2×10-3. But as the upper layer was considered, the ratio showed only a small difference,ranging from 0.79×10-3 to 1.69×10-3.
Water-soluble rare earth elements (WSREEs) of four typical soil profiles in China were determined by using a high-resolution inductively coupled plasma mass spectrometer. Results showed that the contents of WSREEs decreased from upper layer to lower layer of soils in the southern part of China with a high rainfall and low pH but increased for soils in the northern part of China with a low rainfall and relatively higher pH. Contents of WSREEs in soils were lower than 100 μg kg-1 in most casest and varied greatly with both different soils and different layers of the same profile. The highest content was 2816.3 μg kg-1 but the lowest was 17.6 μg kg-1 only. The content of individual rare earth iement (REE) in the soil solution also varied greatly with the highest one ranging from 8.4 to 1373 μg kg-1 for Ce and the lowest one from 0.05to 4.48 μg kg-1 for Lu. The sum of WSREEs in the first soil layers ranged from 121.5 to 345.6 μg kg-1.Great variations existed among ratios of REEs extracted with water to the total REEs of soils, ranging from 0.02×10-3 to 13.2×10-3. But as the upper layer was considered, the ratio showed only a small difference,ranging from 0.79×10-3 to 1.69×10-3.
