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Magnesium (II) Adsorption from Aqueous Solutions on China Clay and the Stability Constants for Complex Formation 被引量:1

Magnesium (Ⅱ) Adsorption from Aqueous Solutions on China Clay and the Stability Constants for Complex Formation
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摘要 China clay was employed as an adsorbent for the removal of Mg 2+ from water at pH 7.0 within the temperature range of 303~328 K. The linearity of the plots indicated Langmuir type isotherms. The reaction was exothermic. A maximum removal of 35% was obtained at 0.50 mmol L -1 metal concentration and a pH of 7.0 at 303 K. The H + rel /Mg 2+ ads ratio changed from a fractional value to 2.5. Strong chemical bondings took place between oxygen atom of the surface and Mg 2+ , resulting in a surface complex species. Temperature had a significant effect on H + rel , and the stability constants also increased with increasing temperature. INTRODUCTIONMagnesiumcompoundsareusedextensivelyforrefractoriesandinsulatingmaterialsaswelasinthemanufactureofrubber,printing...
出处 《Pedosphere》 SCIE CAS CSCD 1998年第2期169-174,共6页 土壤圈(英文版)
关键词 H + releasing Mg 2+ adsorption stability constants temperature 氢离子 镁离子 吸附 稳定性 温度 释放 粘土 水解作用 人类健康
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