异核金属簇合物的研究Ⅱ──铁、钯簇合物的合成与表征

STUDY ON HETERONUCLEAR METAL CLUSTERS Ⅱ ─SYNTHESES AND CHARACTERIZATION OF IRON AND PALLADIUM CLUSTERS

文章报道了Fe2Pd2（CO）；（NO）2（PPh3）2［S2P（OEt）2］2和Fe2Pd2（CO）3（μ2一CO）2（NO）3（PPhs）3［S2P（OEt）2］两个异核簇合物的合成及元素分析、EDS、IR和NMR等表征数据，并对其结构进行了讨论。

Heteronuclear metal cluster I、Fe2Pd2 (CO)4 (NO )2 (PPh3)2 [S2P (OEt )2]2 and Ⅱ、 Fe3Pd2 (CO)3 (μ2, - CO)2(NO )3(PPh3)3[S2P (OEt )2] are preparated. The properties of the clusters are characterized by element analysis, IR. NMR. etc. Their structures are discussed inilially.