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天甲橡胶的等速升温热氧降解研究 被引量:1

THERMOOXIDATIVE DEGRADATION OF METHYL METHACRYLATE-GRAFT-NATURAL RUBBER AT CONASTANT HEATING RATE
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摘要 The thermooxidative degradation of methyl methacry late-graft-natura l rubber(MG) in air was studied by Thermogravimetric Analysis(TGA). The results indicate that the thermooxidative degradation of MG-30 in air has one weight lo ss step change on the whole. The degradation temperatures and the degradation ra tes increase linearly along with the increment of heating rates. The temperature of initial degradation ( t 0) is 0 667 B +351 7 ℃, the temperature at maximum deg radation rate ( t p) is 0 923+385 4 ℃, and the temperature of final degra dation ( t f) is 0 923+385 4 ℃. The degradation rate at t p is not affected by B and its a verage value is 46 7%. However, the degradation rate at t f gains linearly with the increase of B and its average value is 93 0%. The thermooxidative degradation of methyl methacry late-graft-natura l rubber(MG) in air was studied by Thermogravimetric Analysis(TGA). The results indicate that the thermooxidative degradation of MG-30 in air has one weight lo ss step change on the whole. The degradation temperatures and the degradation ra tes increase linearly along with the increment of heating rates. The temperature of initial degradation ( t 0) is 0 667 B +351 7 ℃, the temperature at maximum deg radation rate ( t p) is 0 923+385 4 ℃, and the temperature of final degra dation ( t f) is 0 923+385 4 ℃. The degradation rate at t p is not affected by B and its a verage value is 46 7%. However, the degradation rate at t f gains linearly with the increase of B and its average value is 93 0%.
出处 《华南师范大学学报(自然科学版)》 CAS 2002年第3期103-105,共3页 Journal of South China Normal University(Natural Science Edition)
关键词 等速升温热氧降解 热重分析 天然橡胶 甲基丙烯酸甲酯 接枝共聚 平衡降解温度 methyl methacrylate-graft-natural rubber thermooxidative degradation thermogra vimetric analysis
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