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疏水缔合(丙烯酰胺十六烷基二甲基烯丙基氯化铵-2-丙烯酰胺基-2-甲基丙磺酸)三元共聚物的合成与性能研究 被引量:14

SYNTHESIS AND PERFORMANCE OF HYDROPHOBICALLY ASSOCIATING (ACRYLAMIDE-HEXADECYL ALLY AMMONIUM CHLORIDE-2-|ACRYLAMINO- 2-METHYL PROPANE SUFURIC ACID) TERPOLYMERS
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摘要 Due to the poor salt tolerance and heat resistance of the partially hydrolyzed acryl amide in the reservoir of high temperature and high inorganic salt,and the poor ability of shear,the hydrophobically associating terpolymers acrylamide\|hexadecyl ally ammonium chloride\|2\|acrylamino\|2\|metyl propane sulfuric acid (AM\|C 16 DMAAC\|AMPS) is prepared by micelle polymerization with the nonionic monomer\|AM,the anionic monomer\|AMPS,the cationic monomer\|C 16 DMAAC,It is investigated that the effect of the content of the hydrophobic monomer,anionic monomer,cationic monomer,reaction temperature and the concentration of the inorganic salt and the surfactant on the viscosity of the hydrophobically associating aqueous soluble terpolymers in brine.The results show that the aqueous soluble hydrophobically associating terpolymers(1000?mg/L) have good viscofication effect in brine(20000?mg/L),when the content of the hydrophobic monomer is 1\^2%,and of the anionic monomer is 30%,the hydrophobically associating terpolymers can meet the need of polymer flooding in reservoir of the high concentration inorganic salt. Due to the poor salt tolerance and heat resistance of the partially hydrolyzed acryl amide in the reservoir of high temperature and high inorganic salt, and the poor ability of shear, the hydrophobically associating terpolymers acrylamide-hexadecyl ally ammonium chloride-2-acrylamino-2-metyl propane sulfuric acid (AM-C(16)DMAAC-AMPS) is prepared by micelle polymerization with the nonionic monomer-AM, the anionic monomer-AMPS, the cationic monomer-C(16)DMAAC It is investigated that the effect of the content of the hydrophobic monomer, anionic monomer, cationic monomer, reaction temperature and the concentration of the inorganic salt and the surfactant on the viscosity of the hydrophobically associating aqueous soluble terpolymers in brine. The results show that the aqueous soluble hydrophobically associating terpolymers(1000 mg/L) have good viscofication effect in brine(20000 mg/L), when the content of the hydrophobic monomer is 1.2%, and of the anionic monomer is 30%, the hydrophobically associating terpolymers can meet the need of polymer flooding in reservoir of the high concentration inorganic salt.
出处 《高分子学报》 SCIE CAS CSCD 北大核心 2002年第5期692-694,共3页 Acta Polymerica Sinica
关键词 疏水缔合 丙烯酰胺 十六烷基二甲基烯丙基氯化铵 合成 性能 三元共聚物 2-丙烯酰胺基-2-甲基丙磺酸 聚合物驱油 AM-C-16 DMAAC-AMPS terpolymers hydrophobically associating monomer associating polymer
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