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丝氨酸在蔗糖水溶液中的稀释焓 被引量:6

The Dilution Enthalpies of Serine in Aqueous Sucrose Solutions at 298.15 K
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摘要 利用LKB2277生物活性检测仪分别测定了298.15K时丝氨酸在不同组成的蔗糖水溶液中的稀释焓,利用McMillan-Mayer理论,计算了丝氨酸在不同组成的蔗糖水溶液中的焓对相互作用系数,并与其在葡萄糖水溶液中的焓对相互作用系数h2进行了比较.结果表明,丝氨酸在蔗糖和葡萄糖水溶液中的焓对相互作用系数h2都是负值,并且随着糖浓度的增加,h2系数的绝对值逐渐减少.根据溶质-溶质相互作用和溶质-溶剂相互作用对结果进行了解释. The dilution enthalpies of serine in aqueous sucrose solutions at 298.15 K were measured by LKB 2277 flow microcalorimetry. Using the McMillan-Mayer theory, the enthalpic pair interaction coefficients (h(2)) of serine over whole range of aqueous sucrose solutions have been calculated and compared with the enthalpic pair interaction coefficients of serine in aqueous glucose solutions. It is found that h(2) of serine in aqueous sucrose and h(2) in glucose solutions are negative and become less negative with increasing the concentration of sucrose and glucose. The results are discussed in terms of solute-solute and solute-solvent interactions.
出处 《物理化学学报》 SCIE CAS CSCD 北大核心 2002年第9期825-829,共5页 Acta Physico-Chimica Sinica
基金 国家自然科学基金(29773041)资助项目~~
关键词 丝氨酸 蔗糖水溶液 葡萄糖水溶液 稀释焓 结构相互作用 热力学性质 serine aqueous sucrose solutions aqueous glucose solutions dilution enthalpy structural interactions
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  • 1Hilary E. Kent,Terence H. Lilley,Peter J. Milburn,Michael Bloemendal,Gus Somsen. Interactions between terminally substituted amino acids in an aqueous and a non-aqueous environment. Enthalpic interaction coefficients in water and in N,N-dimethylformamide at 25°C[J] 1985,Journal of Solution Chemistry(2):101~115
  • 2Teresa F. Wegrzyn,Ian D. Watson,Gavin R. Hedwig. Enthalpies of mixing of aqueous solutions of the amino acids glycine, l-alanine and l-serine[J] 1984,Journal of Solution Chemistry(4):233~244
  • 3C. Jolicoeur,B. Riedl,D. Desrochers,L. L. Lemelin,R. Zamojska,O. Enea. Solvation of amino acid residues in water and urea-water mixtures: Volumes and heat capacities of 20 amino acids in water and in 8 molar urea at 25°C[J] 1986,Journal of Solution Chemistry(2):109~128
  • 4Hilary E. Kent,Terence H. Lilley,Peter J. Milburn,Michael Bloemendal,Gus Somsen. Interactions between terminally substituted amino acids in an aqueous and a non-aqueous environment. Enthalpic interaction coefficients in water and in N,N-dimethylformamide at 25°C[J] 1985,Journal of Solution Chemistry(2):101~115
  • 5Teresa F. Wegrzyn,Ian D. Watson,Gavin R. Hedwig. Enthalpies of mixing of aqueous solutions of the amino acids glycine, l-alanine and l-serine[J] 1984,Journal of Solution Chemistry(4):233~244

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