期刊文献+

含氯漂白废水的电氧化处理 被引量:1

Electrochemical Oxidation Treatment of Effluent from Chlorine Bleaching
下载PDF
导出
摘要 以二氧化铅为阳极,不锈钢网为阴极,用电化学氧化法处理多段漂白废水中的有害物质。其中二氧化铅电极是通过在碳棒上电镀而成的。研究发现,废水的电导率和pH值对于不同的废水在电化学氧化过程中的变化是不同的;而废水的COD和色度在整个过程中一直减少;氯化木质素的分子量和分子量分布发生了变化。 A kind of lead-dioxide electrode was prepared by plating lead dioxide on the surface of kryptol. Effluent from chlorine bleaching was disposed by electrochemical oxidation using PbO2 anode, stainless steel web cathode. The results showed that the COD and chroma of effluent decrease in the whole course of electrochemical oxidation. The change of pH value and electrical conductivity is different from different effluent. Aromatic rings of chlorinated lignin can cleavage during electrochemical oxidation. The molecular weight and distribution of the chlorolignin are also changed.
出处 《纤维素科学与技术》 CAS CSCD 2002年第3期40-46,共7页 Journal of Cellulose Science and Technology
基金 中国科学院广州化学研究所纤维素化学重点实验室创新基金资助课题
关键词 造纸 含氯漂白废水 电氧化处理 二氧化铅电极 electrochemical oxidation , effluent treatment, lead dioxide,
  • 相关文献

参考文献11

  • 1Paul F E , Douglas W R. Chlorinate organic matter in bleached chemical pulp production . Tappi J, 1990, 73(1): 179~183
  • 2Shogo Kachi, N Yonese, Y Yoneda. Identifying toxicity from bleacheal hardwood mills. Pulp and Paper Canada, 1980: 81(10): 105
  • 3Knut P Kingstad, Pierr O, Filipe de Sousa, et al. Identification and Mutagenic Properties of Some Chlorinated Aliphatic Compounds in the Spent Liquor from Kraft Pulp Chlorination. Environment Science & Technology, 1981, 15(5): 119
  • 4Walden C C , Howard T E. Toxicity of pulp and paper mill effluent A review of regulations and research. Tappi, 1977, 60(1): 122
  • 5Hilleke J, Springer A M. Industrial environ-mental control, 2nd edn., TAPPI PRESS, Atlanta, Chapter 15, 1993. 305~343
  • 6Man M Springer, Vincent C Hand, Timothy S Jarvis. Electrochemical remove of color and toxicity from bleached kraft effluents. Tappi J, 1995, 78(12): 85~92
  • 7CPPA. Technical Section Standard Method H5P. Color of Pulp Mill Effluents. 1974
  • 8Limosin P D, et al. Electrochemical oxidation of some lignins in basic aqueous solution. Holzforschung, 1986, 40: 31~36
  • 9Chum H L, Baizer M M. The ectrochemistry of biomass and derived materials-electrochemistry of biopolymers derived from biomass. ACS Monograph, 1985, 183: 243~268
  • 10Kharlamova T A, Theodoradze G A. Electro-chemical behavior of phenols. Russian Chemical Reviews, 1987, 56: 16~27

同被引文献19

  • 1杨润昌,周书天.含酚废水湿式电化学氧化处理研究[J].湘潭大学自然科学学报,2001,23(3):55-58. 被引量:6
  • 2Tinucci L, Borgarello E, et al. Treatment of industrial wastewaters by photocatalytic oxidation on TiO2, photocatalytic purification and treatment of water and elsevier science publishers [J]. Amsterdam, 1993: 585.
  • 3Mansilla H D, et al. ZnO-catalytsed photodegration of kraft black liquor[J]. Photochem, 1994, (78): 267.
  • 4M Cristina Yeber, Jaime Rodriguez, Juanita Freer, et al. Photocatalytic degradation of cellulose bleaching effluent by supoported TiO2 and ZnO [J]. Chemosphere,2000, 41:1 193.
  • 5Perez M, et al. Photocatalytic treatment of paper pulp bleach effluents[J]. Quim Anal, 1997, 16 (3): 211.
  • 6W H Glaze. Drinking water treatment with ozone [J].Environ Sci and Technol, 1987,21:224.
  • 7Zimmerman. New waste disposal process[J]. Chem Eng,1958, 65(8).
  • 8Foussard J N, Debellefontaine H, et al. Efficient elimination of organic liquid wastes: Wet air oxidation [J].Environ Eng, 1989,115(2): 367-385.
  • 9Emanuel N M, Denisof E T, Maizus J R. Liquid phase oxidation of hydrocarbons [M]. Plenum Press, Now York:1967.
  • 10Fujishima A, Honda K. Electrochemical photolysis of water at a semiconductor electode[J]. nature, 1972, 238(5358): 37-38.

引证文献1

二级引证文献7

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部