单取代杯[6]芳烃衍生物的合成与表征

Syntheses and Characterization of Mono-substituted Calixarenes Derivatives

系统地研究了在各种不同反应体系与条件下杯 [6 ]芳烃与含酯基、环氧基、溴代烷基等活性基团化合物的选择性功能化反应行为 ,发现分别在K2 CO3 甲苯以及KOH 乙腈体系中能以较好产率得到了具酯基、环氧基、溴代烷基的单取代杯 [6 ]芳烃高分子单体 .

Syntheses of several mono-substituted calix[6]arenes containing the active groups are studied under many different reaction conditions. It is found that mono-substituted calix[6]arenes containing ester groups, epoxy groups or bromo alkyl groups can be obtained in 25%, 30% and 35% yields, respectively, in toluene with K2CO3 as base or in actonitrile with KOH as base.