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咪唑类Schiff碱配体及其含Mn配合物的合成及表征

Synthesis and characterization of imidazole schiff base and its manganese complexes
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摘要 The new imidazole schiff base C 11 N 4H 10 and its three intermediates,as well as four complexes of Mn(C 11 N 4H 10 ) 2(ClO 4) 2·6H 2O,Mn(C 11 N 4H 10 ) 3(ClO 4) 2·2H 2O,[Mn 3(μ 3 O)(CH 3COO) 6(C 4H 6N 2) 3]CH 3COO·2H 2O·C 2H 5OH and [Mn 3O(O 2CC 6H 5) 6(C 4H 6N 2) 3]ClO 4·2H 2O were synthesized and characterized by the means of FTIR,UB VIS and EA. The new imidazole schiff base C 11 N 4H 10 and its three intermediates,as well as four complexes of Mn(C 11 N 4H 10 ) 2(ClO 4) 2·6H 2O,Mn(C 11 N 4H 10 ) 3(ClO 4) 2·2H 2O,[Mn 3(μ 3 O)(CH 3COO) 6(C 4H 6N 2) 3]CH 3COO·2H 2O·C 2H 5OH and [Mn 3O(O 2CC 6H 5) 6(C 4H 6N 2) 3]ClO 4·2H 2O were synthesized and characterized by the means of FTIR,UB VIS and EA.
出处 《化学研究与应用》 CAS CSCD 北大核心 2002年第5期569-571,共3页 Chemical Research and Application
基金 陕西省教育厅专项科研基金 ( 0 1JK0 78)
关键词 咪唑类Schiff碱 配体 合成 表征 含锰金属酶 模型配合物 锰配合物 manganese enzyme model complex imidazole manganese complex
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  • 1Li X,Inorg Chem,1989年,28卷,3403页

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