摘要
本文运用群论方法,对 ML_(11)型配合物的价键结构进行了探讨,导出了该类型配合物中央体的σ杂化方式及杂化轨道的波函数,此外,还详细分析了每一种σ杂化方式中的原子轨道,从而推断.只有镧系或者锕系元素作为中央体时,才能形成 ML_(11)型配合物.
Using the group theory,this paper has a discussion on the valence bond structure of ML_(11) type complex and derives the o hybrid fashion of central atoms and the wave functions of the hy- bridized orbitals.In addition,the atom orbit of each kind of o hybrid fashion is analyzed,from which we deduce that only lanthanides or actinides elements as central atoms can form the ML_(11) type complex.
关键词
价键结构
配合物
中心原子
杂化
波函数
valence bond structure
complex
central atom
hybrid
wave function
