N-乙酰基-N-苯酰基二茂铁基腙的ⅡB族和主族金属螯合物

IIB and Main Group Metal Chelates of N-Acetyl-N benzoyl-ferrocenyl Hydrazone

芳酰腙及其金属配合物的生物活性研究,自50年代起已有不少报道。1983年前后Patil和Sen等制备了几个含二茂铁基的芳酰腙,并研究了它们与某些金属离子的配位作用。本文报道N-乙酰基-N-苯酰基二茂铁基腙[Fe—C(CH_3)=NNH—COC_6H_5,Fe=C_5H_5FeC_5H_4]的IIB族和某些主族金属螫合物。

Six title chelates ML_2(M=Zn, Cd, Hg and Pb)and ML [M=C_6H_5Hg, Tl; L= FcC(CH_3)=N--N=C (C_6H_5) O^-] have been synthesized. Their composition and structure are determined by means of IR, ~1H NMR, MS and elemental analyses.