双齿杂环胺酞花菁铁(Ⅱ)盐配合物的吸收谱分析及电导

The Absorption Spectrum Analysis and Electric Conductivities of Phthalocyaninato-Fe^(2+) Polymerized via a Bidentate Bridging Heterocyclic Amine

假设双齿杂环胺酞花菁铁(Ⅱ)盐配合物(FePcL)_n具有D_(4h)对称性。通过对其吸收谱分析,得到了晶场参量D_q和配合物结构间的关系,从而关联观测电导值和配合物结构。在谱分析中利用了减少可调参量数目的技巧,以增加理论分析的可靠性。

Based on the assumption that the polymeric phthalocyaninato-Fe^(2+) bidentate heterocyolic amine complex (FePcL)_n possess a D_(4h) symmetry. From the analysis of absorption spectra the relation between the crystal field parameter and the structure of complex (FePcL)_n has been obtained. Consequently, the relation between the observed electric conductivity and structure variations in (FePcL)_n is found. A method for reducing the number of parameters is used and the reliability of theoretical analysis is increased.