热脱附-气相色谱-质谱法应用于工业源废气中挥发性有机物的目标和非目标筛查

Target and non-target screening of volatile organic compounds in industrial exhaust gas using thermal desorption-gas chromatography-mass spectrometry

建立了固相吸附热脱附-气相色谱-质谱(TD-GC-MS)综合筛查工业源废气中挥发性有机物(VOCs)的方法。对两种型号的固相吸附管进行了比较,最终选择使用Tenax SS TD Tubes吸附管。气体样品以恒定流速通过吸附管,富集分析物,经热脱附后,用GC-MS进行检测,目标化合物以内标法定量,非目标化合物的含量以甲苯的响应系数计算。方法检出限为1.06~5.44 ng,以采样体积300 mL计算,目标化合物的检出限为0.004~0.018 mg/m^3。吸附管平均加标回收率为78.4%~89.4%,相对标准偏差为3.9%~14.4%(n=7)。应用该方法对大连市某垃圾焚烧发电厂排放的废气进行VOCs目标及非目标化合物综合筛查,共检出29种VOCs,其中仅5种VOCs为预先设定的目标化合物,另外24种为非目标化合物,5种目标化合物含量仅占所有检出物总量的26.7%。证明了工业源废气VOCs分析中非目标化合物筛查的重要性,该研究思路对完整测定工业源挥发性有机污染物分布具有一定的借鉴意义。

A method of comprehensive screening of the target and non-target volatile organic compounds(VOCs)in industrial exhaust gas using thermal desorption-gas chromatography-mass spectrometry(TD-GC-MS)has been developed.In this paper,two types of solid phase adsorption column were compared,and the Tenex SS TD Tube was selected.The analytes were enriched into the adsorption tube by constant flow sampling,and detected by TD-GC-MS in full scan mode.Target compounds were quantified by internal standard method,and the quantities of non-target compounds were calculated by response coefficient of toluene.The method detec-tion limits(MDLs)for the24VOCs were1.06to5.44ng,and MDLs could also be expressed as0.004to0.018mg/m3assuming that the sampling volume was300mL.The average recoveries were in the range of78.4%to89.4%with the relative standard deviations(RSDs)of3.9%to14.4%(n=7).The established analytical method was applied for the comprehensive screening of VOCs in a waste incineration power plant in Dalian city.Twenty-nine VOCs were identified.In these compounds,only five VOCs were the target compounds set in advance,which accoun-ted for26.7%of the total VOCs identified.Therefore,this study further proved the importance of screening non-target compounds in the analysis of VOCs in industrial exhaust gas,and has certain reference significance for the complete determ ination of VOCs distribution.