摘要
Metallurgical modeling of microalloying boron behavior in nickel-based superalloys during pre-weld heat treatment and welding has been systematically established. Non-equilibrium grain boundary resegregation is physically coupled with non-equilibrium solidification of the weld pool for improved quantitative understanding of the imminent detriment of boron near the as-transformed grain boundary of the mushy zone and weldability. A strategic priority of the reduction in boron through low heat input and pre-weld heat treatment to suppress massive boride nucleation and grain boundary liquation are introduced.Both factors are capable of reducing the material response to boron-assisted intergranular liquation cracking at the high-energy sites of the grain-coarsened heat-affected zone( HAZ) beneath the surface and are of practical importance to provide robust integrity of joints. The synergistic self-repairment arterial crack network with the crystallographic substructure of the backfill enables amelioration of the HAZ crack resistance. The theoretical predictions are in satisfactory agreement with the phenomenological microanalysis, indirectly. This metallurgical modeling is also applicable to other high-temperature aerospace materials with similar metallurgical properties.
Metallurgical modeling of microalloying boron behavior in nickel-based superalloys during pre-weld heat treatment and welding has been systematically established. Non-equilibrium grain boundary resegregation is physically coupled with non-equilibrium solidification of the weld pool for improved quantitative understanding of the imminent detriment of boron near the as-transformed grain boundary of the mushy zone and weldability. A strategic priority of the reduction in boron through low heat input and pre-weld heat treatment to suppress massive boride nucleation and grain boundary liquation are introduced.Both factors are capable of reducing the material response to boron-assisted intergranular liquation cracking at the high-energy sites of the grain-coarsened heat-affected zone( HAZ) beneath the surface and are of practical importance to provide robust integrity of joints. The synergistic self-repairment arterial crack network with the crystallographic substructure of the backfill enables amelioration of the HAZ crack resistance. The theoretical predictions are in satisfactory agreement with the phenomenological microanalysis, indirectly. This metallurgical modeling is also applicable to other high-temperature aerospace materials with similar metallurgical properties.