Dielectric properties and point defect behavior of antimony oxide doped Ti deficient barium strontium titanate ceramics

氧化锑掺杂贫Ti钛酸锶钡陶瓷的介电性能及缺陷行为（英文）

The microstructures and dielectric properties of Sb2O3-doped Ti deficient barium strontium titanate ceramics prepared by solid state method were investigated with non-stoichiometric level and Sb2O3content by SEM,XRD and LCR measure system.It is found that with the increase ofδ,(Ba0.75Sr0.25)Ti1-δO3-2δceramics transform from single phase solid solutions with typical cubic perovskite structure to multiphase compounds while(Ba0.75Sr0.25)Ti0.998O2.996ceramics remain to be single-phase with the increasing Sb2O3content.The distortion of the ABO3perovskite lattice caused by VTi″″and VO..induces the drop of Curie temperature and the rise of relative dielectric constant in(Ba0.75Sr0.25)Ti1-δO3-2δceramics with increasingδvalue.The orientation of VO??elastic dipoles results in the domain-wall pinning and thus the reduction of the dielectric loss.With increasing Sb2O3content,the relative dielectric constant,dielectric constant maximum and Curie temperature of(Ba0.75Sr0.25)Ti0.998O2.996ceramics decrease dramatically while the dielectric loss increases.

采用固相法制备Sb_2O_3掺杂的贫Ti钛酸锶钡陶瓷,通过SEM、XRD和LCR测试系统研究其显微结构及介电性能随非化学计量比及Sb_2O_3含量的变化。结果表明:随着δ值增大,(Ba_(0.75)Sr_(0.25))Ti_(1-δ)O_(3-2δ)陶瓷由典型立方钙钛矿结构单相固溶体转变为多相化合物,而(Ba_(0.75)Sr_(0.25))Ti_(0.998)O_(2.996)陶瓷随Sb_2O_3掺杂量增加始终为单相固溶体。由V_(Ti)^(″″)及V_O^(··)引起的ABO_3型钙钛矿晶胞畸变导致(Ba_(0.75)Sr_(0.25))Ti_(1-δ)O_(3-2δ)陶瓷随δ值增大居里温度降低且相对介电常数增高。弹性偶极子V_O^(··)的定向引起畴壁钉扎而导致其介电损耗降低。(Ba_(0.75)Sr_(0.25))Ti_(0.998)O_(2.996)陶瓷的相对介电常数、介电常数最大值及居里温度均随着Sb_2O_3掺杂量增加显著降低而其介电损耗却随Sb_2O_3掺杂量的增加而增大。