摘要
采用柠檬酸燃烧法制备了Ho,Yb∶(La Lu)_2O_3纳米粉体,确定了其制备的适宜条件。制得的粉体分散性较好,粒径均匀,平均粒径约为55 nm。研究了掺杂不同摩尔分数Ho^(3+)和Yb^(3+)对粉体荧光光谱的影响,980nm泵浦源激发下得到的粉体的上转换光谱显示,粉体发出484 nm蓝光(~5F_3→~5I_8)、551 nm绿光(~5S_2/~5F_4→~5I_8)、660 nm红光(~5F_5→~5I_8)。并讨论了掺杂离子Ho^(3+)-Yb^(3+)的上转换发光机制。
The powders of Ho,Yb∶(LaLu)2O 3 were prepared by citric acid combustion method.The preparation conditions of the powders were determined.The as-prepared particles are of near-spherical shape,and weak agglomeration,the average particle size was about 55 nm.The effects of different mole fraction Ho 3+and Yb 3+on the fluorescence spectra of the powders were studied.Under the excitation of 980 nm,the powders can emit blue-ray appeared at 484 nm,corresponding to the energy level transition of Ho 3+from 5F 3 to 5I 8,green light appeared at 551 nm,corresponding to the energy level transition of Ho 3+from 5S 2/5F 4 to 5I 8,and red light at 660 nm,corresponding to the energy level transition of Ho 3+from 5F 5 to 5I 8.The upconversion luminescence mechanism of Ho 3+-Yb 3+in co-doped system was discussed.
作者
李剑
代雨航
朱忠丽
张莹
LI Jian;DAI Yu-hang;ZHU Zhong-li;ZHANG Ying(Chemistry and Environmental Engineering College,Changchun University of Science and Technology,Changchun 130022,China;Changchun Institute of Optics,Fine Mechanics and Physics,Chinese Academy of Sciences,Changchun 130033,China)
出处
《发光学报》
EI
CAS
CSCD
北大核心
2018年第3期301-306,共6页
Chinese Journal of Luminescence
基金
吉林省科技发展计划(20170204028GX)资助项目~~
关键词
钬镱双掺氧化镧镥
上转换光谱
能级跃迁
holmium ytterbium co-doped lanthanum lutetium oxide
upcoversion spectrum
energy transfer