摘要
Through electrospinning,La_2Co Mn O_6 nanofibers were prepared from a polyvinylpyrrolidone/lanthanum nitrate–cobalt acetate–manganese acetate(PVP/LCM)precursor and were used as electrode materials.The morphologies and structures of the samples were characterized by field-emission scanning electron microscopy(FE-SEM),transmission electron microscopy(TEM),X-ray diffraction(XRD),and Brunauer-Emmett-Teller(BET)specific surface area analysis.The results show that the prepared La_2Co Mn O_6 nanofibers are stable,one-dimensional structures formed from interconnected La_2Co Mn O_(6 )nanoparticles with a diamond-like crystal structure.The specific surface area of the fibers is 79.407 m^2·g^(-1).Electrochemical performance tests with a three-electrode system reveal the specific capacitance of the La_2Co Mn O_6 nanofibers as 109.7 F·g^(-1) at a current density of 0.5 A·g^(-1).After 1000 charge-discharge cycles at a current density of 1 A·g^(-1),the specific capacitance maintains 90.9%of its initial value,demonstrating a promising performance of the constraint capacitance and good cyclic stability.
Through electrospinning,La_2Co Mn O_6 nanofibers were prepared from a polyvinylpyrrolidone/lanthanum nitrate–cobalt acetate–manganese acetate(PVP/LCM)precursor and were used as electrode materials.The morphologies and structures of the samples were characterized by field-emission scanning electron microscopy(FE-SEM),transmission electron microscopy(TEM),X-ray diffraction(XRD),and Brunauer-Emmett-Teller(BET)specific surface area analysis.The results show that the prepared La_2Co Mn O_6 nanofibers are stable,one-dimensional structures formed from interconnected La_2Co Mn O_(6 )nanoparticles with a diamond-like crystal structure.The specific surface area of the fibers is 79.407 m^2·g^(-1).Electrochemical performance tests with a three-electrode system reveal the specific capacitance of the La_2Co Mn O_6 nanofibers as 109.7 F·g^(-1) at a current density of 0.5 A·g^(-1).After 1000 charge-discharge cycles at a current density of 1 A·g^(-1),the specific capacitance maintains 90.9%of its initial value,demonstrating a promising performance of the constraint capacitance and good cyclic stability.
基金
financially supported by the Natural Science Foundation of Liaoning Province,China (No.201602113)
the Scientific Research Project of Liaoning Education Department (No.L2013177)
the National Natural Science Foundation of China (No.21106012)
