摘要
采用钛离子掺杂钙钛矿薄膜的方法修饰钙钛矿晶界缺陷。研究表明钛离子富集在晶界处,有效地钝化了晶界缺陷,同时有助于连续、平整、高质量薄膜的形成。经过钛离子掺杂后的钙钛矿太阳能电池电流(JSC)达到22.3 mA·cm^(-2),开路电压(VOC)达1.1 V,填充因子(FF)高达72.4%,光电转换效率(PCE)优化至17.4%,远高于未掺杂钙钛矿太阳能电池。
The grain boundaries defect is solved by titanium ion(Ti^4+)doping.Ti4+has small radius which is proved to form at the grain boundary of polycrystalline perovskite.By control doping of titanium ion,grain size become more uniform,which leads to more continuous perovskite thin film.Studies suggest that the defects in grain boundary of polycrystalline perovskite are passivated by doping Ti4+,which results in the trap states concentration greatly decrease.And experimental test clearly exhibits more excellent performance of short-circuit current density(JSC=22.3 mA·cm^-2),open-circuit voltage(VOC=1.10 V),fill factor(FF=72.4%)and photovoltaic conversion efficiency(PCE=17.4%)with low amount Ti4+doping compared with pure planar heterojunction perovskite solar cells(AM1.5).
作者
田辉
熊启
刘鹏
张京
韩磊
张宇豪
郑永进
吴立爽
诸跃进
TIAN Hui;XIONG Qi;LIU Peng;ZHANG Jing;HAN Lei;ZHANG Yu-Hao;ZHENG Yong-Jin;WU Li-Shuang;ZHU Yue-Jin(Department of Microelectronic Science and Engineering,Faculty of Science,Ningbo University,Ningbo,Zhejiang 315211,China)
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2018年第9期1710-1718,共9页
Chinese Journal of Inorganic Chemistry
基金
国家自然科学基金(No.11374168,11547033)、省自然科学基金(No.LY18F040004)、国家留学归国人员基金和宁波大学王宽诚基金项目资助。
关键词
钙钛矿太阳能电池
钛掺杂
缺陷态
晶界
perovskite solar cells
Ti4+doping
defect states
grain boundary