摘要
以金属钴盐、2-羟基-1,3,5-苯基三羧酸(OH-H_3BTC)为原料,在碱性条件下,通过水热方法合成了一个钴配位聚合物[Co_2(O-BTC)(H_2O)_5]_n(1),并利用X射线粉末和单晶衍射、红外光谱、元素分析以及热重等方法对该化合物进行了表征。化合物1含有线性四核单元[Co_4O_7],四核单元内的金属离子是通过羧酸氧原子和羟基氧原子桥联的。该四核单元进一步通过O-BTC^(4-)配体在ab平面上形成一个二维层状结构,相邻的层与层通过氢键作用形成一个三维超分子结构。热重分析结果显示化合物1在100℃开始失重。磁性研究表明,化合物1中相邻的钴离子之间存在反铁磁性相互作用。
The hydrothermal reaction of cobalt(Ⅱ)salts with 2-hydroxyl-1,3,5-benzenetricarboxylic acid(OH-H3BTC)in the presence of sodium hydroxide afforded a cobalt(Ⅱ)coordination polymer,namely[Co2(O-BTC)(H2O)5]n(1),which has been characterized by powder and single-crystal X-ray diffraction,infrared spectroscopy,elemental analysis,and thermogravimetric analysis.Compound 1 contains a linear tetranuclear unit[Co4O7]through the carboxylate oxygen and hydroxyl atoms,which are further linked to form a two-dimensional(2D)layered structure in the ab plane by the O-BTC4-organic ligands.Adjacent layers are packed along the c-axis with the hydrogen bond interactions dominating between the layers to form a three-dimensional(3D)supramolecular structure.Thermal analysis reveals that 1 begins to lose weight at ca.100℃.Magnetic studies reveal that dominant antiferromagnetic interactions are dominated between the magnetic centers in 1.CCDC:1841028.
作者
汪鹏飞
WANG Peng-Fei(School of Chemistry and Material Engineering,Chizhou University,Chizhou,Anhui 247000,China;State Key Laboratory of Coordination Chemistry,Nanjing University,Nanjing 210023,China)
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2018年第9期1747-1752,共6页
Chinese Journal of Inorganic Chemistry
基金
国家自然科学基金(No.21101019)
安徽省高校自然科学研究重点项目(No.KJ2018A0576)
安徽省高校优秀人才支持计划重点项目(No.gxyqZD2016371)
南京大学配位化学国家重点实验室开放基金(No.SKLCC1805)资助
关键词
配位聚合物
磁性
四核钴簇
coordination polymer
magnetic properties
tetranuclear cobalt(Ⅱ)-cluster