卟啉分子识别中的非共价键相互作用

Non-covalent Interaction in Molecular Recognition of Porphyrin:an Overview

卟啉由于其特殊的分子识别性能在超分子材料化学领域得到了广泛的应用。本文综述了近年来卟啉化合物的分子识别研究,详细介绍了卟啉化合物进行分子识别过程中的非共价键相互作用,重点探讨了氢键、配位、π-π堆积以及静电等相互作用在卟啉分子识别中的作用,并对卟啉分子识别的前景进行了展望。

Porphyrins have been widely used in the field of supramolecular chemistry due to their special molecular recognition properties.This paper provides a comprehensive review about the present researches on the molecular recognition of porphyrin compounds.The non-covalent interactions in molecular recognition progress of porphyrin compounds are introduced in detail.In particular,the hydrogen bonding,coordination,π-πstacking and electrostatic interaction are discussed with emphasis.In addition,the potential development of porphyrin molecular recognition is proposed.